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The Story of Tennessine: Discovery of a New Chemical Element | Jim Roberto | TEDxUTK


so element 117 officially joined the

so element 117 officially joined the periodic table in 2016 the name

periodic table in 2016 the name

periodic table in 2016 the name Tennessee n– was chosen to reflect the

Tennessee n– was chosen to reflect the

Tennessee n– was chosen to reflect the contributions of the tennessee region to

contributions of the tennessee region to

contributions of the tennessee region to the discovery the ending i and ii is

the discovery the ending i and ii is

the discovery the ending i and ii is characteristic of column 17 elements

characteristic of column 17 elements

characteristic of column 17 elements like chlorine fluorine and now tennessee

like chlorine fluorine and now tennessee

like chlorine fluorine and now tennessee n– in fact you would have thought

n– in fact you would have thought

n– in fact you would have thought perhaps that the name would have been

perhaps that the name would have been

perhaps that the name would have been tennessee ‘m that’s what we what we what

tennessee ‘m that’s what we what we what

tennessee ‘m that’s what we what we what we’re used to in terms of new elements

we’re used to in terms of new elements

we’re used to in terms of new elements but the chemist told us oh no group 17

but the chemist told us oh no group 17

but the chemist told us oh no group 17 this has to end in irony the result

this has to end in irony the result

this has to end in irony the result could not have been achieved without

could not have been achieved without

could not have been achieved without international collaboration and this

international collaboration and this

international collaboration and this required unique facilities both in

required unique facilities both in

required unique facilities both in Russia and in the United States it also

Russia and in the United States it also

Russia and in the United States it also required a team of physicists chemists

required a team of physicists chemists

required a team of physicists chemists and engineers more than 100 in both

and engineers more than 100 in both

and engineers more than 100 in both countries adding a new element to the

countries adding a new element to the

countries adding a new element to the periodic table is very exciting and also

periodic table is very exciting and also

periodic table is very exciting and also a significant scientific accomplishment

a significant scientific accomplishment

a significant scientific accomplishment but the element 117 discovery was much

but the element 117 discovery was much

but the element 117 discovery was much more than that it also advanced the

more than that it also advanced the

more than that it also advanced the understanding of nuclei with extreme

understanding of nuclei with extreme

understanding of nuclei with extreme numbers of protons and neutrons

numbers of protons and neutrons

numbers of protons and neutrons including the decay products from

including the decay products from

including the decay products from element 1 117 11 new loop new nuclei

element 1 117 11 new loop new nuclei

element 1 117 11 new loop new nuclei were added to the nuclear chart and it

were added to the nuclear chart and it

were added to the nuclear chart and it also forced that foreshadows the

also forced that foreshadows the

also forced that foreshadows the discovery of even heavier elements

element 117 is a so-called super-heavy

element 117 is a so-called super-heavy element this term is refers to elements

element this term is refers to elements

element this term is refers to elements with more than 103 protons with Seaborg

with more than 103 protons with Seaborg

with more than 103 protons with Seaborg who predicted the existence of

who predicted the existence of

who predicted the existence of super-heavy elements in the 1960s and he

super-heavy elements in the 1960s and he

super-heavy elements in the 1960s and he realized that new facilities would be

realized that new facilities would be

realized that new facilities would be required for heavy element chemistry and

required for heavy element chemistry and

required for heavy element chemistry and so he proposed the development of a high

so he proposed the development of a high

so he proposed the development of a high flux reactor and radio chemical

flux reactor and radio chemical

flux reactor and radio chemical processing center at Oak Ridge National

processing center at Oak Ridge National

processing center at Oak Ridge National Laboratory to advance this research and

Laboratory to advance this research and

Laboratory to advance this research and his vision turns out to have been very

his vision turns out to have been very

his vision turns out to have been very important for this discovery which comes

important for this discovery which comes

important for this discovery which comes more than 50 years later Seberg also

more than 50 years later Seberg also

more than 50 years later Seberg also predicted the existence of an island of

predicted the existence of an island of

predicted the existence of an island of stability for super-heavy elements you

stability for super-heavy elements you

stability for super-heavy elements you may recall from high school chemistry

may recall from high school chemistry

may recall from high school chemistry that atoms with closed shells of

that atoms with closed shells of

that atoms with closed shells of electrons are more stable think than

electrons are more stable think than

electrons are more stable think than think the noble gases well it turns out

think the noble gases well it turns out

think the noble gases well it turns out that nuclei have shells of protons and

that nuclei have shells of protons and

that nuclei have shells of protons and and neutrons and those nuclei with

and neutrons and those nuclei with

and neutrons and those nuclei with closed shells of protons and and

closed shells of protons and and

closed shells of protons and and neutrons have stronger binding the last

neutrons have stronger binding the last

neutrons have stronger binding the last stable isotope led 2:08 has a closed

stable isotope led 2:08 has a closed

stable isotope led 2:08 has a closed shell for both neutrons and protons well

shell for both neutrons and protons well

shell for both neutrons and protons well we can imagine we can calculate where

we can imagine we can calculate where

we can imagine we can calculate where the next closed shells would be can we

the next closed shells would be can we

the next closed shells would be can we get there and if we could get there what

get there and if we could get there what

get there and if we could get there what would the lifetimes be some theories

would the lifetimes be some theories

would the lifetimes be some theories predict that the lifetime would be

predict that the lifetime would be

predict that the lifetime would be millions of years that’s very exciting

millions of years that’s very exciting

millions of years that’s very exciting so we are on a journey not only to

so we are on a journey not only to

so we are on a journey not only to discover new elements but also define

discover new elements but also define

discover new elements but also define long-lived elements beyond the known

long-lived elements beyond the known

long-lived elements beyond the known periodic table at the island of

periodic table at the island of

periodic table at the island of stability so what are the key questions

stability so what are the key questions

stability so what are the key questions the key questions are where does the

the key questions are where does the

the key questions are where does the periodic table end we don’t know what is

periodic table end we don’t know what is

periodic table end we don’t know what is the limit of the number of protons and

the limit of the number of protons and

the limit of the number of protons and neutrons a nucleus can contain

neutrons a nucleus can contain

neutrons a nucleus can contain we don’t know do super-heavy elements

we don’t know do super-heavy elements

we don’t know do super-heavy elements have special nuclear properties and

have special nuclear properties and

have special nuclear properties and special chemical properties we expect so

special chemical properties we expect so

special chemical properties we expect so and does the predicted island of

and does the predicted island of

and does the predicted island of stability exist and one of the important

stability exist and one of the important

stability exist and one of the important results of this work is a very strong

results of this work is a very strong

results of this work is a very strong indication that it does so how do you

indication that it does so how do you

indication that it does so how do you make a super-heavy element well you can

make a super-heavy element well you can

make a super-heavy element well you can do it around your kitchen table all you

do it around your kitchen table all you

do it around your kitchen table all you need to do is find a combination of two

need to do is find a combination of two

need to do is find a combination of two atoms that when you combine their

atoms that when you combine their

atoms that when you combine their protons they add to the number of

protons they add to the number of

protons they add to the number of protons you want in your new element and

protons you want in your new element and

protons you want in your new element and then you smash these two atoms together

then you smash these two atoms together

then you smash these two atoms together in a high-energy accelerator and for for

in a high-energy accelerator and for for

in a high-energy accelerator and for for element 117 an intense beam of a special

element 117 an intense beam of a special

element 117 an intense beam of a special isotope of calcium what is directed at a

isotope of calcium what is directed at a

isotope of calcium what is directed at a berkland target now Burke Liam is an

berkland target now Burke Liam is an

berkland target now Burke Liam is an artificial element has to be made

artificial element has to be made

artificial element has to be made artificially at an energy of around 250

artificially at an energy of around 250

artificially at an energy of around 250 MeV now if you look at the at the

MeV now if you look at the at the

MeV now if you look at the at the representation at the bottom of the

representation at the bottom of the

representation at the bottom of the slide we’re starting with a calcium 48

slide we’re starting with a calcium 48

slide we’re starting with a calcium 48 nucleus which has 20 protons we’re

nucleus which has 20 protons we’re

nucleus which has 20 protons we’re impacting it on a Brooklyn 249 nucleus

impacting it on a Brooklyn 249 nucleus

impacting it on a Brooklyn 249 nucleus which has 97 protons and 20 plus 97

which has 97 protons and 20 plus 97

which has 97 protons and 20 plus 97 equals 117 so on rare occasions these

equals 117 so on rare occasions these

equals 117 so on rare occasions these fuse they create a compound nucleus in a

fuse they create a compound nucleus in a

fuse they create a compound nucleus in a very excited state and the trick is for

very excited state and the trick is for

very excited state and the trick is for that compound nucleus to survive long

that compound nucleus to survive long

that compound nucleus to survive long enough that you can discover the new

enough that you can discover the new

enough that you can discover the new elements so in in our case the choice of

elements so in in our case the choice of

elements so in in our case the choice of the calcium 48 in Berkeley in 249 was

the calcium 48 in Berkeley in 249 was

the calcium 48 in Berkeley in 249 was key because these both have very large

key because these both have very large

key because these both have very large excesses in number of neutrons so that

excesses in number of neutrons so that

excesses in number of neutrons so that compound nucleus has many extra neutrons

compound nucleus has many extra neutrons

compound nucleus has many extra neutrons before it can fly apart it sheds energy

before it can fly apart it sheds energy

before it can fly apart it sheds energy by shedding those extra neutrons and

by shedding those extra neutrons and

by shedding those extra neutrons and that’s why element 117 exists

that’s why element 117 exists

that’s why element 117 exists so what did it take to produce a few

so what did it take to produce a few

so what did it take to produce a few atoms of element 117 well you remember

atoms of element 117 well you remember

atoms of element 117 well you remember the calcium 48 it it is a naturally

the calcium 48 it it is a naturally

the calcium 48 it it is a naturally occurring isotope of calcium but it’s

occurring isotope of calcium but it’s

occurring isotope of calcium but it’s very rare so it has to be enriched by

very rare so it has to be enriched by

very rare so it has to be enriched by 500 times then you need to produce 20

500 times then you need to produce 20

500 times then you need to produce 20 milligrams of Burk Liam to 249 an

milligrams of Burk Liam to 249 an

milligrams of Burk Liam to 249 an element that does not exist in nature

element that does not exist in nature

element that does not exist in nature this was produced by Neutron irradiation

this was produced by Neutron irradiation

this was produced by Neutron irradiation over almost a year in the world’s

over almost a year in the world’s

over almost a year in the world’s highest thermal Neutron flux at Oak

highest thermal Neutron flux at Oak

highest thermal Neutron flux at Oak Ridge National Laboratory this is

Ridge National Laboratory this is

Ridge National Laboratory this is followed by a very delicate chemical

followed by a very delicate chemical

followed by a very delicate chemical separation because what comes out out of

separation because what comes out out of

separation because what comes out out of the reactor has lots of stuff in it and

the reactor has lots of stuff in it and

the reactor has lots of stuff in it and it’s very radioactive this chemical

it’s very radioactive this chemical

it’s very radioactive this chemical separation has to be done behind three

separation has to be done behind three

separation has to be done behind three feet of concrete it takes about six

feet of concrete it takes about six

feet of concrete it takes about six weeks and and the final material has to

weeks and and the final material has to

weeks and and the final material has to be purified to one part in ten to the

be purified to one part in ten to the

be purified to one part in ten to the seven then you have to produce targets

seven then you have to produce targets

seven then you have to produce targets that can survive heavy ion beam

that can survive heavy ion beam

that can survive heavy ion beam irradiation and then you actually array

irradiation and then you actually array

irradiation and then you actually array v8 those targets for 150 days in the in

v8 those targets for 150 days in the in

v8 those targets for 150 days in the in the world’s highest in the world’s most

the world’s highest in the world’s most

the world’s highest in the world’s most intense calcium 48 beam which is

intense calcium 48 beam which is

intense calcium 48 beam which is available at the floor off laboratory in

available at the floor off laboratory in

available at the floor off laboratory in termina Russia major the major

termina Russia major the major

termina Russia major the major facilities at Oak Ridge and Dubner were

facilities at Oak Ridge and Dubner were

facilities at Oak Ridge and Dubner were essential to this experiment and the

essential to this experiment and the

essential to this experiment and the what’s what’s pictured here is the heavy

what’s what’s pictured here is the heavy

what’s what’s pictured here is the heavy ion cyclotron at Dubna and the reactor

ion cyclotron at Dubna and the reactor

ion cyclotron at Dubna and the reactor chemical separation complex at all grids

chemical separation complex at all grids

chemical separation complex at all grids the same complex that was seaborg’s

the same complex that was seaborg’s

the same complex that was seaborg’s vision more than 100 scientists and

vision more than 100 scientists and

vision more than 100 scientists and engineers contributed to the discovery

engineers contributed to the discovery

engineers contributed to the discovery this includes scientists from Dubna from

this includes scientists from Dubna from

this includes scientists from Dubna from Oak Ridge from Lawrence Livermore

Oak Ridge from Lawrence Livermore

Oak Ridge from Lawrence Livermore National Lab from the University of

National Lab from the University of

National Lab from the University of Tennessee and from Vanderbilt and from

Tennessee and from Vanderbilt and from

Tennessee and from Vanderbilt and from the University of Nevada in addition

the University of Nevada in addition

the University of Nevada in addition more than 100 technical staff

more than 100 technical staff

more than 100 technical staff at Oakridge and a governor were needed

at Oakridge and a governor were needed

at Oakridge and a governor were needed to support the berkeley impression and

to support the berkeley impression and

to support the berkeley impression and the separation and and separation and

the separation and and separation and

the separation and and separation and the accelerator campaign in russia

the accelerator campaign in russia

the accelerator campaign in russia pictured are the the scientists and

pictured are the the scientists and

pictured are the the scientists and engineers who performed the chemical

engineers who performed the chemical

engineers who performed the chemical separation at Oakridge and in the circle

separation at Oakridge and in the circle

separation at Oakridge and in the circle is actually a picture of the 20

is actually a picture of the 20

is actually a picture of the 20 milligrams of berkeley ‘m that was

milligrams of berkeley ‘m that was

milligrams of berkeley ‘m that was produced it’s that little green dot if

produced it’s that little green dot if

produced it’s that little green dot if you can see it at the very bottom of the

you can see it at the very bottom of the

you can see it at the very bottom of the glass vial so six atoms of element 117

glass vial so six atoms of element 117

glass vial so six atoms of element 117 were produced in the first campaign how

were produced in the first campaign how

were produced in the first campaign how did we know we had element 117 well we

did we know we had element 117 well we

did we know we had element 117 well we produce two isotopes of element 1 1 1 1

produce two isotopes of element 1 1 1 1

produce two isotopes of element 1 1 1 1 17 1 with a hundred and seventy-seven

17 1 with a hundred and seventy-seven

17 1 with a hundred and seventy-seven neutrons the other with 176 these

neutrons the other with 176 these

neutrons the other with 176 these isotopes decay into nine additional

isotopes decay into nine additional

isotopes decay into nine additional heaviest isotopes of elements 115-113

heaviest isotopes of elements 115-113

heaviest isotopes of elements 115-113 111 etc by subsequent by sequential

111 etc by subsequent by sequential

111 etc by subsequent by sequential alpha particle II emissions this decays

alpha particle II emissions this decays

alpha particle II emissions this decays chain provides a unique signature for

chain provides a unique signature for

chain provides a unique signature for element 117 the likelihood that that

element 117 the likelihood that that

element 117 the likelihood that that sequence of events could be produced at

sequence of events could be produced at

sequence of events could be produced at random is less than 1 in a million

now we talked earlier about the island

now we talked earlier about the island of stability and as we approach it we

of stability and as we approach it we

of stability and as we approach it we expect the lifetimes to increase so the

expect the lifetimes to increase so the

expect the lifetimes to increase so the element 117 experiment provided an

element 117 experiment provided an

element 117 experiment provided an opportunity for us to test this by

opportunity for us to test this by

opportunity for us to test this by looking at previous data and then in the

looking at previous data and then in the

looking at previous data and then in the and the new data from the decays

and the new data from the decays

and the new data from the decays development 1 1 117 so for a particular

development 1 1 117 so for a particular

development 1 1 117 so for a particular isotope for particularly element element

isotope for particularly element element

isotope for particularly element element 113 we we now have a span of isotopes

113 we we now have a span of isotopes

113 we we now have a span of isotopes spanning 8 neutral Neutron numbers from

spanning 8 neutral Neutron numbers from

spanning 8 neutral Neutron numbers from the

the

the lightest to the heaviest what happens as

lightest to the heaviest what happens as

lightest to the heaviest what happens as we add neutrons to that element 1:13

we add neutrons to that element 1:13

we add neutrons to that element 1:13 isotope well the lifetimes are going out

isotope well the lifetimes are going out

isotope well the lifetimes are going out and over that sequence of eight neutron

and over that sequence of eight neutron

and over that sequence of eight neutron numbers the lifetime actually went up by

numbers the lifetime actually went up by

numbers the lifetime actually went up by a factor of seven thousand you would

a factor of seven thousand you would

a factor of seven thousand you would have expected without an island of

have expected without an island of

have expected without an island of stability for the lifetimes actually to

stability for the lifetimes actually to

stability for the lifetimes actually to be going down and so this is the

be going down and so this is the

be going down and so this is the strongest evidence we have to date of

strongest evidence we have to date of

strongest evidence we have to date of the existence of the island of stability

the data that we got is very consistent

the data that we got is very consistent you can look from these charts at how

you can look from these charts at how

you can look from these charts at how well it it fits the air is outlined in

well it it fits the air is outlined in

well it it fits the air is outlined in blue is the new data added from these

blue is the new data added from these

blue is the new data added from these experiments so it’s a significant

experiments so it’s a significant

experiments so it’s a significant increase in our understanding of the

increase in our understanding of the

increase in our understanding of the nuclear landscape for the heaviest

nuclear landscape for the heaviest

nuclear landscape for the heaviest elements and it also continues the trend

elements and it also continues the trend

elements and it also continues the trend of increased stability for increasing

of increased stability for increasing

of increased stability for increasing Neutron numbers now we got a bonus when

Neutron numbers now we got a bonus when

Neutron numbers now we got a bonus when we discovered an element 117 because we

we discovered an element 117 because we

we discovered an element 117 because we also discovered element 115 which is the

also discovered element 115 which is the

also discovered element 115 which is the decay product of element 1 117 so we got

decay product of element 1 117 so we got

decay product of element 1 117 so we got 2 4 1 and it is very fitting that the

2 4 1 and it is very fitting that the

2 4 1 and it is very fitting that the names chosen for these two elements were

names chosen for these two elements were

names chosen for these two elements were Tennyson in recognition of the

Tennyson in recognition of the

Tennyson in recognition of the contributions of Oak Ridge National Lab

contributions of Oak Ridge National Lab

contributions of Oak Ridge National Lab Vanderbilt and and the University of

Vanderbilt and and the University of

Vanderbilt and and the University of Tennessee and moscovia in recognition of

Tennessee and moscovia in recognition of

Tennessee and moscovia in recognition of the come of the contributions made by

the come of the contributions made by

the come of the contributions made by our collaborators in Russia there were

our collaborators in Russia there were

our collaborators in Russia there were two other elements that were named at

two other elements that were named at

two other elements that were named at the same time okay listen

the same time okay listen

the same time okay listen which is element 118 it is named for

which is element 118 it is named for

which is element 118 it is named for Yuri ogen Sen who is the scientific

Yuri ogen Sen who is the scientific

Yuri ogen Sen who is the scientific leader of the floor off laboratory and

leader of the floor off laboratory and

leader of the floor off laboratory and the key partner in these experiments

the key partner in these experiments

the key partner in these experiments excuse me

and neoneun which was discovered in

and neoneun which was discovered in japan yuri organ essien is one of two

japan yuri organ essien is one of two

japan yuri organ essien is one of two living persons who has ever had an

living persons who has ever had an

living persons who has ever had an element named after him the other beat

element named after him the other beat

element named after him the other beat SeaWorld

SeaWorld

SeaWorld so in summary two new elements with

so in summary two new elements with

so in summary two new elements with atomic numbers 115 and 117 have been

atomic numbers 115 and 117 have been

atomic numbers 115 and 117 have been synthesized they demonstrate increased

synthesized they demonstrate increased

synthesized they demonstrate increased stability with increasing Neutron number

stability with increasing Neutron number

stability with increasing Neutron number longer half-lives will enable single

longer half-lives will enable single

longer half-lives will enable single element chemistry on these new atoms we

element chemistry on these new atoms we

element chemistry on these new atoms we are at the shores of the fabled island

are at the shores of the fabled island

are at the shores of the fabled island of stability and new a new elements up

of stability and new a new elements up

of stability and new a new elements up to element 120 are within our sights the

to element 120 are within our sights the

to element 120 are within our sights the next steps let’s go to higher atomic

next steps let’s go to higher atomic

next steps let’s go to higher atomic numbers let’s go to higher neutron

numbers let’s go to higher neutron

numbers let’s go to higher neutron numbers we are working now on special

numbers we are working now on special

numbers we are working now on special isotopes of element 118 which would be

isotopes of element 118 which would be

isotopes of element 118 which would be the heaviest nuclei ever produced

the heaviest nuclei ever produced

the heaviest nuclei ever produced and we are searching for new elements

and we are searching for new elements

and we are searching for new elements 119 and 120 super-heavy elements are

119 and 120 super-heavy elements are

119 and 120 super-heavy elements are important because they offer the

important because they offer the

important because they offer the potential for new physics new chemistry

potential for new physics new chemistry

potential for new physics new chemistry and new material science using atoms

and new material science using atoms

and new material science using atoms previously unknown that have extreme

previously unknown that have extreme

previously unknown that have extreme numbers of electrons protons and

numbers of electrons protons and

numbers of electrons protons and neutrons element 117 is a very

neutrons element 117 is a very

neutrons element 117 is a very significant step toward that island of

significant step toward that island of

significant step toward that island of stability and the continued progress in

stability and the continued progress in

stability and the continued progress in this area rests on the shoulders of a

this area rests on the shoulders of a

this area rests on the shoulders of a community of scientists and engineers

community of scientists and engineers

community of scientists and engineers who harness the power of international

who harness the power of international

who harness the power of international collaboration thank you and the last is

collaboration thank you and the last is

collaboration thank you and the last is the latest version of the periodic table

the latest version of the periodic table

the latest version of the periodic table thank you

thank you

thank you [Applause]

”

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